| 內容摘要 | In this study three synthetic routes of bisbiphenyl acylphosphine oxide were proposed and practiced from CDOP(10-chloro-9,10-dihydro-9-oxa-10-phosphaphenanthrene).(i) CDOP was first reacted to MDOP(6-methoxy-(6H)-dibenz[c,e][1,2]oxaphosphorin).,then the Arbuzov reaction was followed.(ii) DOPO(9,10-Dihydro-9-oxa-10- phosphaphen- anthrene-10-oxide) was obtained from CDOP,then it was reacted with aromatic aldehyde to a secondary alcohol and finally oxidation reaction was proceeded .(iii) At the beginning CDOP was oxidized to CDOPO(6-chloro-dibenz[c,e][1,2]oxaphosphorin-6-oxide),after that Grignard reaction or Wurtz reaction was taken and vice versa.. |